JEE Main · 2020 · Shift-IeasyPERI-085

The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively, are:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively, are:

Options
  1. a

    296,325,333-296, -325, -333 and 349-349

  2. b

    349,333,325-349, -333, -325 and 296-296

  3. c

    333,349,325-333, -349, -325 and 296-296

  4. d

    333,325,349-333, -325, -349 and 296-296

Correct Answerc

333,349,325-333, -349, -325 and 296-296

Detailed Solution

🧠 Halogen ΔegH\Delta_{eg}H values in kJ/mol: F = 328-328, Cl = 349-349, Br = 325-325, I = 296-296. The order asked is F, Cl, Br, I — match the values to the elements in that exact order Most exothermic is Cl (not F!) due to F's 2p2p repulsion anomaly. Br is just below F in magnitude, and I is the least exothermic of the four halogens. Memorize the four numbers.

(Note: some sources cite F as 333kJ/mol-333\,kJ/mol. The textbook used here lists F = 333-333 — accept that for this question.)

🗺️ Match the option Question asks for F, Cl, Br, I in that order. F = 333-333, Cl = 349-349, Br = 325-325, I = 296-296. That is option (c): 333,349,325,296-333, -349, -325, -296.

Other options: (b) 349,333,325,296-349, -333, -325, -296 → this is Cl, F, Br, I order. Wrong sequence. (d) 333,325,349,296-333, -325, -349, -296 → this swaps Cl and Br. Cl is more exothermic than Br.

⚠️ The trap Option (b) puts 349-349 first — the most negative number sits at the front. Students assume "F is the smallest halogen, so F has the most negative EGE" and mark this. Wrong: the most negative value belongs to Cl (not F). Always remember the F anomaly: the 2p2p repulsion makes F's EGE LESS negative than Cl's.

Answer: (c)\boxed{\text{Answer: (c)}}

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The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively, are: (JEE Main 2020) | Canvas Classes