The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively, are:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively, are:
- a
and
- b
and
- c✓
and
- d
and
and
🧠 Halogen values in kJ/mol: F = , Cl = , Br = , I = . The order asked is F, Cl, Br, I — match the values to the elements in that exact order Most exothermic is Cl (not F!) due to F's repulsion anomaly. Br is just below F in magnitude, and I is the least exothermic of the four halogens. Memorize the four numbers.
(Note: some sources cite F as . The textbook used here lists F = — accept that for this question.)
🗺️ Match the option Question asks for F, Cl, Br, I in that order. F = , Cl = , Br = , I = . That is option (c): .
Other options: (b) → this is Cl, F, Br, I order. Wrong sequence. (d) → this swaps Cl and Br. Cl is more exothermic than Br.
⚠️ The trap Option (b) puts first — the most negative number sits at the front. Students assume "F is the smallest halogen, so F has the most negative EGE" and mark this. Wrong: the most negative value belongs to Cl (not F). Always remember the F anomaly: the repulsion makes F's EGE LESS negative than Cl's.
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