JEE Main · 2022 · Shift-IIeasyPERI-060

The first ionization enthalpies of Be, B, N and O follow the order:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The first ionization enthalpies of Be, B, N and O follow the order:

Options
  1. a

    \ceB<\ceBe<\ceO<\ceN\ce{B} < \ce{Be} < \ce{O} < \ce{N}

  2. b

    \ceO<\ceN<\ceB<\ceBe\ce{O} < \ce{N} < \ce{B} < \ce{Be}

  3. c

    \ceBe<\ceB<\ceN<\ceO\ce{Be} < \ce{B} < \ce{N} < \ce{O}

  4. d

    \ceB<\ceBe<\ceN<\ceO\ce{B} < \ce{Be} < \ce{N} < \ce{O}

Correct Answera

\ceB<\ceBe<\ceO<\ceN\ce{B} < \ce{Be} < \ce{O} < \ce{N}

Detailed Solution

🧠 Two anomalies in this set: Be > B (filled 2s22s^2) and N > O (half-filled 2p32p^3) Across Period 2, IE1IE_1 rises overall, but two breaks interrupt it. Group 2 (Be) is higher than Group 13 (B) because removing an electron from filled 2s22s^2 is harder than from a lone 2p12p^1. Group 15 (N) is higher than Group 16 (O) because half-filled 2p32p^3 has extra symmetry stability that beats the paired-electron repulsion in 2p42p^4.

🗺️ Build the order B has the lone 2p12p^1 — easiest to remove. Be has filled 2s22s^2 — harder than B. O has 2p42p^4 with one paired orbital — pair repulsion makes it easier than N. N has half-filled 2p32p^3 — hardest in this set.

So: \ceB<\ceBe<\ceO<\ceN\ce{B} < \ce{Be} < \ce{O} < \ce{N}.

⚠️ The trap Option (d) \ceB<\ceBe<\ceN<\ceO\ce{B} < \ce{Be} < \ce{N} < \ce{O} catches the Be–B anomaly but forgets the N–O one. It places O above N, following the simple "IEIE rises across" rule. Wrong — the half-filled 2p32p^3 in N is more stable than the 2p42p^4 of O, so N is harder to ionize. Both anomalies must be applied at the same time.

Answer: (a)\boxed{\text{Answer: (a)}}

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