The first ionization enthalpies of Be, B, N and O follow the order:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
The first ionization enthalpies of Be, B, N and O follow the order:
- a✓
- b
- c
- d
🧠 Two anomalies in this set: Be > B (filled ) and N > O (half-filled ) Across Period 2, rises overall, but two breaks interrupt it. Group 2 (Be) is higher than Group 13 (B) because removing an electron from filled is harder than from a lone . Group 15 (N) is higher than Group 16 (O) because half-filled has extra symmetry stability that beats the paired-electron repulsion in .
🗺️ Build the order B has the lone — easiest to remove. Be has filled — harder than B. O has with one paired orbital — pair repulsion makes it easier than N. N has half-filled — hardest in this set.
So: .
⚠️ The trap Option (d) catches the Be–B anomaly but forgets the N–O one. It places O above N, following the simple " rises across" rule. Wrong — the half-filled in N is more stable than the of O, so N is harder to ionize. Both anomalies must be applied at the same time.
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