Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion…
d & f-Block Elements · Class 12 · JEE Main Previous Year Question
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): In aqueous solutions is reducing while is oxidising in nature. Reason (R): Extra stability to half filled electronic configuration is observed than incompletely filled electronic configuration.
In the light of the above statement, choose the most appropriate answer from the options given below:
- a✓
Both (A) and (R) are true and (R) is the correct explanation of (A)
- b
Both (A) and (R) are true but (R) is not the correct explanation of (A)
- c
(A) is false but (R) is true
- d
(A) is true but (R) is false
Both (A) and (R) are true and (R) is the correct explanation of (A)
Assertion (A): is reducing; is oxidising — TRUE ✓
- () readily loses an electron to become (, stable) → reducing agent
- () readily gains an electron to become (, half-filled stable) → oxidising agent
Reason (R): Half-filled configuration has extra stability over incompletely filled — TRUE ✓
Is R the correct explanation of A? YES ✓
- () → (): gains stability (not half-filled but is stable due to exchange energy)
- () → (): gains half-filled stability → strong driving force to oxidise
The extra stability of the half-filled configuration directly explains why is a strong oxidising agent.
Answer: Option (1) — Both true, R is correct explanation
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