JEE Main · 2024 · Shift-IImediumDNF-055

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion…

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): In aqueous solutions Cr2+\text{Cr}^{2+} is reducing while Mn3+\text{Mn}^{3+} is oxidising in nature. Reason (R): Extra stability to half filled electronic configuration is observed than incompletely filled electronic configuration.

In the light of the above statement, choose the most appropriate answer from the options given below:

Options
  1. a

    Both (A) and (R) are true and (R) is the correct explanation of (A)

  2. b

    Both (A) and (R) are true but (R) is not the correct explanation of (A)

  3. c

    (A) is false but (R) is true

  4. d

    (A) is true but (R) is false

Correct Answera

Both (A) and (R) are true and (R) is the correct explanation of (A)

Detailed Solution

Assertion (A): Cr2+\text{Cr}^{2+} is reducing; Mn3+\text{Mn}^{3+} is oxidising — TRUE

  • Cr2+\text{Cr}^{2+} (3d43d^4) readily loses an electron to become Cr3+\text{Cr}^{3+} (3d33d^3, stable) → reducing agent
  • Mn3+\text{Mn}^{3+} (3d43d^4) readily gains an electron to become Mn2+\text{Mn}^{2+} (3d53d^5, half-filled stable) → oxidising agent

Reason (R): Half-filled configuration has extra stability over incompletely filled — TRUE

Is R the correct explanation of A? YES ✓

  • Cr2+\text{Cr}^{2+} (3d43d^4) → Cr3+\text{Cr}^{3+} (3d33d^3): gains stability (not half-filled but 3d33d^3 is stable due to exchange energy)
  • Mn3+\text{Mn}^{3+} (3d43d^4) → Mn2+\text{Mn}^{2+} (3d53d^5): gains half-filled stability → strong driving force to oxidise

The extra stability of the half-filled 3d53d^5 configuration directly explains why Mn3+\text{Mn}^{3+} is a strong oxidising agent.

Answer: Option (1) — Both true, R is correct explanation

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