JEE Main · 2019 · Shift-IIeasyEC-022

A solution of Ni(NO3)2 is electrolyzed between platinum electrodes using 0.1 Faraday electricity. How many mole of Ni…

Electrochemistry · Class 12 · JEE Main Previous Year Question

Question

A solution of Ni(NO3)2\mathrm{Ni(NO_3)_2} is electrolyzed between platinum electrodes using 0.1 Faraday electricity. How many mole of Ni will be deposited at the cathode?

Options
  1. a

    0.10

  2. b

    0.15

  3. c

    0.05

  4. d

    0.20

Correct Answerc

0.05

Detailed Solution

Strategy: Use Faraday's Law to relate the amount of electricity (in Faradays) to the moles of metal deposited. Identify the valen\ce (zz) of the Nickel ion from the given formula.

Step 1: Determine the charge on Nickel From \ceNi(NO3)2\ce{Ni(NO3)_2}, the nickel ion is \ceNi2+\ce{Ni^{2+}}. The reduction half-reaction is: \ceNi2++2eNi(s)\ce{Ni^{2+} + 2e^- \rightarrow Ni(s)} This means 2 moles of electrons (2 F2\ \mathrm{F}) are required to deposit 1 mole of Nickel.

Step 2: Calculate moles for 0.1 Faraday n\ceNi=Quantity of electricityValen\ceof ion=0.1 F2 F/moln_{\ce{Ni}} = \frac{\text{Quantity of electricity}}{\text{Valen\ce of ion}} = \frac{0.1\ \mathrm{F}}{2\ \mathrm{F/mol}} n\ceNi=0.05 moln_{\ce{Ni}} = 0.05\text{ mol}

Answer: (c) 0.05\boxed{\text{Answer: (c) 0.05}}

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