JEE Main · 2024 · Shift-IIeasyHC-076

The incorrect statement regarding ethyne is:

Hydrocarbons · Class 11 · JEE Main Previous Year Question

Question

The incorrect statement regarding ethyne is:

Options
  1. a

    The \ceCC\ce{C-C} bond in ethyne is shorter than that in ethene.

  2. b

    Both carbons are sp\text{sp} hybridised.

  3. c

    Ethyne is linear.

  4. d

    The carbon-carbon bond in ethyne is weaker than that in ethene.

Correct Answerd

The carbon-carbon bond in ethyne is weaker than that in ethene.

Detailed Solution

Step 1: Analyze Each Statement

(a) C-C bond in ethyne shorter than ethene? Triple bond length ~1.20 A vs double bond ~1.34 A. Shorter in ethyne. (a) CORRECT.

(b) Both carbons sp hybridised? Triple bond = sp hybridization. (b) CORRECT.

(c) Ethyne is linear? sp carbons give 180 degree bond angle. (c) CORRECT.

(d) C-C bond in ethyne weaker than in ethene? Triple bond (bond order 3) is stronger than double bond (bond order 2). Bond energy: C≡C ~835 kJ/mol vs C=C ~612 kJ/mol. (d) INCORRECT -- triple bond is stronger, not weaker.

Key Points:

  • Higher bond order = shorter bond length AND stronger bond
  • Ethyne triple bond is both shorter and stronger than ethene double bond

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