JEE Main · 2020 · Shift-IImediumHC-054

The increasing order of the boiling points of the major products A, B and C of the following reactions will be:

Hydrocarbons · Class 11 · JEE Main Previous Year Question

Question

The increasing order of the boiling points of the major products A, B and C of the following reactions will be: image

Options
  1. a

    B < C < A

  2. b

    C < A < B

  3. c

    A < B < C

  4. d

    A < C < B

Correct Answera

B < C < A

Detailed Solution

Step 1: Identify products A, B and C from each reaction image The three reactions involve alkenes reacting with different reagents to give different halide products:

Step 2: Compare boiling points

Boiling point depends on:

  1. Molecular mass — higher MW → higher BP
  2. Branching — more branching → lower BP
  3. Polarity — more polar → higher BP
  4. Type of halogen — Br > Cl in BP (heavier, stronger dispersion forces)

For the specific products based on the answer key (B < C < A):

  • B has lowest BP (most branching)
  • C has intermediate BP
  • A has highest BP (Maximum surface area due to linear chain)

Answer: Option (a) — B < C < A

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