JEE Main · 2023 · Shift-IImediumHC-037

The one giving maximum number of isomeric alkenes on dehydrohalogenation reaction is (excluding rearrangement):

Hydrocarbons · Class 11 · JEE Main Previous Year Question

Question

The one giving maximum number of isomeric alkenes on dehydrohalogenation reaction is (excluding rearrangement):

Options
  1. a

    1-Bromo-2-methylbutane

  2. b

    2-Bromopropane

  3. c

    2-Bromopentane

  4. d

    2-Bromo-3,3-dimethylpentane

Correct Answerc

2-Bromopentane

Detailed Solution

Step 1: Recall dehydrohalogenation (E2 elimination)

Dehydrohalogenation removes \ceHX\ce{HX} to form alkenes. The number of isomeric alkenes depends on the number of distinct β\beta-hydrogens available.

image Answer: Option (c)

Key Points to Remember:

  • Count distinct β\beta-carbons with H atoms to determine number of elimination products
  • Geometric isomers (cis/trans) count as separate alkenes
  • Quaternary carbons have no β\beta-H, so no elimination possible from that side

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