JEE Main · 2019 · Shift-IeasyPB11-053

The basic structural unit of feldspar, zeolites, mica, and asbestos is:

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

The basic structural unit of feldspar, zeolites, mica, and asbestos is:

Options
  1. a

    [SiO4]4[\mathrm{SiO_4}]^{4-}

  2. b

    image

  3. c

    [SiO3]2[\mathrm{SiO_3}]^{2-}

  4. d

    SiO2\mathrm{SiO_2}

Correct Answera

[SiO4]4[\mathrm{SiO_4}]^{4-}

Detailed Solution

Strategy: Identify the basic structural unit (monomeric unit) common to all silicate minerals: feldspar, zeolites, mica, and asbestos.

Step 1: Silicate Structure All silicate minerals are built from the [\ceSiO4]4[\ce{SiO4}]^{4-} tetrahedron as the fundamental unit. In this unit:

  • Silicon is at the centre in tetrahedral geometry (sp3sp^3)
  • Four oxygen atoms surround it
  • Overall charge: 4(Si)+4(2)(O)=48=44(\text{Si}) + 4(-2)(\text{O}) = 4 - 8 = -4, so the unit is [\ceSiO4]4[\ce{SiO4}]^{4-}

Step 2: How Minerals Differ Different silicate minerals arise from sharing of corners of these tetrahedra:

  • Feldspar, mica, asbestos, zeolites all derive their structures from corner-sharing of [\ceSiO4]4[\ce{SiO4}]^{4-} units in different ways.

The basic building block common to all = \ce[SiO4]4\ce{[SiO4]^{4-}}

Answer: (A) [\ceSiO4]4\boxed{\text{Answer: (A) }[\ce{SiO4}]^{4-}}

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