JEE Main · 2019 · Shift-IIeasyPB11-014

The hydride that is NOT electron deficient is:

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

The hydride that is NOT electron deficient is:

Options
  1. a

    SiH4\mathrm{SiH_4}

  2. b

    B2H6\mathrm{B_2H_6}

  3. c

    GaH3\mathrm{GaH_3}

  4. d

    AlH3\mathrm{AlH_3}

Correct Answera

SiH4\mathrm{SiH_4}

Detailed Solution

Strategy: Identify which hydride is NOT electron-deficient by comparing electron counts.

Step 1: Classifying Hydrides A hydride is electron-deficient if the central atom has fewer than 8 electrons in its valence shell:

  • \ceB2H6\ce{B2H6} (Boron): B has only 3 valence e⁻; diborane is electron-deficient. ❌
  • \ceAlH3\ce{AlH3} (Aluminium): Al has 3 valence e⁻; AlH₃ is electron-deficient. ❌
  • \ceGaH3\ce{GaH3} (Gallium): Similarly electron-deficient. ❌
  • \ceSiH4\ce{SiH4} (Silicon): Si has 4 valence e⁻ + 4 from H = 8 electrons — complete octet. It is an electron-precise (not electron-deficient) hydride. ✅

Answer: (A) \ceSiH4\boxed{\text{Answer: (A) }\ce{SiH4}}

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