JEE Main · 2020 · Shift-ImediumPB11-046

'X' melts at low temperature and is a bad conductor of electricity in both liquid and solid state. X is:

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

'X' melts at low temperature and is a bad conductor of electricity in both liquid and solid state. X is:

Options
  1. a

    zinc sulphide

  2. b

    Mercury

  3. c

    Silicon carbide

  4. d

    Carbon tetrachloride

Correct Answerd

Carbon tetrachloride

Detailed Solution

Strategy: Identify the substance that melts at low temperature and is a bad conductor of electricity in both solid and liquid states.

Step 1: Analysing the Properties

  • "Melts at low temperature" → Low melting point → likely a molecular compound (not ionic or covalent network).
  • "Bad conductor in solid AND liquid" → eliminates metals and ionic compounds (ionic compounds conduct in liquid state). This points to a non-ionic, non-metallic substance.

Step 2: Evaluating Options

  • Zinc sulphide (\ceZnS\ce{ZnS}): Ionic, conducts electricity in liquid state. ❌
  • Mercury (\ceHg\ce{Hg}): Metal, good conductor in liquid state. ❌
  • Silicon carbide (\ceSiC\ce{SiC}): Covalent network solid, extremely high melting point (~2730 °C). ❌
  • Carbon tetrachloride (\ceCCl4\ce{CCl4}): Covalent molecular compound, low melting point (−23 °C), bad conductor in both solid and liquid states (no ions or free electrons). ✅

Answer: (D) Carbon tetrachloride (\ceCCl4)\boxed{\text{Answer: (D) Carbon tetrachloride (}\ce{CCl4}\text{)}}

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