JEE Main · 2024 · Shift-IImediumPB12-079

Choose the correct statements from the following: A. All group 16 elements form oxides of general formula EO2 and EO3…

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

Choose the correct statements from the following:

A. All group 16 elements form oxides of general formula EO2\mathrm{EO_2} and EO3\mathrm{EO_3} where E=S,Se,Te\mathrm{E = S, Se, Te} and Po. Both the types of oxides are acidic in nature.

B. TeO2\mathrm{TeO_2} is an oxidising agent while SO2\mathrm{SO_2} is reducing in nature.

C. The reducing property decreases from H2S\mathrm{H_2S} to H2Te\mathrm{H_2Te} down the group.

D. The ozone molecule contains five lone pairs of electrons.

Choose the correct answer from the options given below:

Options
  1. a

    A and D only

  2. b

    B and C only

  3. c

    C and D only

  4. d

    A and B only

Correct Answerd

A and B only

Detailed Solution

Strategy: Evaluate the accuracy of statements regarding Group 16 elements and Ozone properties.

Step 1: Statement Analysis

  • A: True. \ceS,Se,Te,Po\ce{S, Se, Te, Po} form dioxides and trioxides. They are generally acidic (though heavier dioxides are amphoteric).
  • B: True. Down the group, reducing character of dioxides decreases and oxidizing character increases. \ceSO2\ce{SO2} is a reducing agent while \ceTeO2\ce{TeO2} acts as an oxidant.
  • C: False. Reducing property of hydrides increases from \ceH2S\ce{H2S} to \ceH2Te\ce{H2Te} as MHM-H bond dissociation enthalpy decreases.
  • D: False. The Ozone molecule (\ceO3)(\ce{O3}) contains 6 lone pairs (1 on central, 2 and 3 on outer oxygens).

Step 2: Conclusion Only statements A and B are correct.

Answer: (Option) [d] A and B only\boxed{\text{Answer: (Option) [d] A and B only}}

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