JEE Main · 2021 · Shift-IImediumPB12-101

Which one of the following correctly represents the order of stability of oxides, X2O; (X = halogen)?

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

Which one of the following correctly represents the order of stability of oxides, X2O\mathrm{X_2O}; (X\mathrm{X} = halogen)?

Options
  1. a

    Cl>I>Br\mathrm{Cl > I > Br}

  2. b

    Br>Cl>I\mathrm{Br > Cl > I}

  3. c

    I>Cl>Br\mathrm{I > Cl > Br}

  4. d

    Br>I>Cl\mathrm{Br > I > Cl}

Correct Answerc

I>Cl>Br\mathrm{I > Cl > Br}

Detailed Solution

Strategy: Compare the stability of halogen oxides based on their formula type and periodic trends.

Step 1: Halogen Oxide Stability The order of stability for halogen oxides follows the trend: I > Cl > Br\text{I > Cl > Br}.

  • Iodine oxides are stable due to the large size and high polarizability of Iodine (thermodynamic stability).
  • Chlorine oxides are stable due to kinetic factors (many have pπdπp\pi-d\pi bonding).
  • Bromine oxides are the least stable as they lack both thermodynamic and kinetic stability factors.

Step 2: Order Selection Matching the given order (\ceI>Cl>Br)(\ce{I > Cl > Br}) for oxides like \ceX2O\ce{X2O} yields the answer.

Answer: (Option) [c] \ceI>Cl>Br\boxed{\text{Answer: (Option) [c] $\ce{I > Cl > Br}$}}

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