JEE Main · 2021 · Shift-IIhardATOM-056

According to Bohr's atomic theory: (A) Kinetic energy of electron Z2n2 (B) The product of velocity (v) of electron and…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

According to Bohr's atomic theory:

(A) Kinetic energy of electron Z2n2\propto \frac{Z^2}{n^2} (B) The product of velocity (v) of electron and principal quantum number (n), vnZ2|vn| \propto Z^2 (C) Frequency of revolution of electron in an orbit Z3n3\propto \frac{Z^3}{n^3} (D) Coulombic force of attraction on the electron Z3n4\propto \frac{Z^3}{n^4}

Choose the most appropriate answer:

Options
  1. a

    (A), (C) and (D) only

  2. b

    (A) and (D) only

  3. c

    (C) only

  4. d

    (A) only

Correct Answerb

(A) and (D) only

Detailed Solution

🧠 The Fundamental Constants Audit Everything in the Bohr model—velocity, energy, force, frequency—is a power function of ZZ and nn. We need to verify the exponents for four key properties.

🗺️ The Exponent Scan

  • (A) KE Z2/n2\propto Z^2/n^2: Energy is always based on the square of ZZ over the square of nn. Correct.
  • (B) Product vnZ2|vn| \propto Z^2: vZ/nv \propto Z/n, so vn(Z/n)n=Zv \cdot n \propto (Z/n) \cdot n = Z. This claims Z2Z^2. Incorrect.
  • (C) Frequency fZ3/n3f \propto Z^3/n^3: f=v/2πrf = v/2\pi r. Ratio (Z/n)/(n2/Z)=Z2/n3(Z/n) / (n^2/Z) = Z^2/n^3. This claims Z3/n3Z^3/n^3. Incorrect.
  • (D) Coulombic Force FZ3/n4F \propto Z^3/n^4: FZ/r2F \propto Z/r^2. Ratio Z/(n2/Z)2=Z3/n4Z / (n^2/Z)^2 = Z^3/n^4. Correct.

Valid statements are (A) and (D).

The "Third Power Filter" Notice that only the Force reaches the Z3Z^3 power because it depends on r2r^2. Most properties in Bohr (Energy, a0a_0) keep ZZ at first or second power. The Z3/n4Z^3/n^4 pattern for force is a unique fingerprint worth memorizing.

⚠️ Common Traps Mixing up Frequency and Velocity! Students often think everything about "motion" (vv and ff) must have the same ratio. But frequency accounts for the circumference (rr), introducing another factor of n2/Zn^2/Z.

Answer: (b)\boxed{\text{Answer: (b)}}

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According to Bohr's atomic theory: (A) Kinetic energy of electron Z2n2 (B) The product of velocity… (JEE Main 2021) | Canvas Classes