JEE Main · 2019 · Shift-ImediumATOM-069

Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H atom is…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H atom is suitable for this purpose?

[RH=1×105R_H = 1 \times 10^5 cm1^{-1}, h=6.6×1034h = 6.6 \times 10^{-34} Js, c=3×108c = 3 \times 10^8 ms1^{-1}]

Options
  1. a

    Paschen, 3\infty \to 3

  2. b

    Paschen, 535 \to 3

  3. c

    Balmer, 2\infty \to 2

  4. d

    Lyman, 1\infty \to 1

Correct Answera

Paschen, 3\infty \to 3

Detailed Solution

🧠 The Infrared Match 900 nm is in the Infrared region. In the Hydrogen spectrum, transitions ending at n=1n=1 (Lyman) are UV, and those ending at n=2n=2 (Balmer) are mostly Visible. For muscular pain (heat treatment), we need Infrared, which corresponds to the Paschen series (n=3n=3).

🗺️ The Calculation Verification

  1. Given RHR_H: 1×105 cm1=107 m11 \times 10^5 \text{ cm}^{-1} = 10^7 \text{ m}^{-1} (This is an approximation for 1.097×1071.097 \times 10^7).
  2. Testing Paschen Limit (n=3n = \infty \to 3): νˉ=R(1320)=1059 cm1\bar{\nu} = R \left( \frac{1}{3^2} - 0 \right) = \frac{10^5}{9} \text{ cm}^{-1}
  3. Wavelength: λ=9105 cm=9×105 cm=900 nm\lambda = \frac{9}{10^5} \text{ cm} = 9 \times 10^{-5} \text{ cm} = 900 \text{ nm} This matches the criteria exactly.

The "Heat = IR" Logic In competitive exams, remember:

  • Lyman = Sterilization/UV
  • Balmer = Vision/Light
  • Paschen/Brackett = Muscular Pain/Remotes/Heat/Infrared The "900 nm" value is a huge hint. 700+ nm is IR. Paschen starts there.

⚠️ Common Traps Don't get tricked into calculating the frequency! The question gives λ=900\lambda = 900 nm. Use the Rydberg formula in its wave number form directly. Using the given simplified RHR_H value is critical; using 1.0971.097 would give 820\sim 820 nm, which might make you doubt your answer.

Answer: (A)\boxed{\text{Answer: (A)}}

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