Identify the incorrect statement from the following:
Structure of Atom · Class 11 · JEE Main Previous Year Question
Identify the incorrect statement from the following:
- a
A circular path around the nucleus in which an electron moves is proposed as Bohr's orbit.
- b
An orbital is the one electron wave function.
- c
The existence of Bohr's orbits is supported by hydrogen spectrum.
- d✓
Atomic orbital is characterised by the quantum numbers and only.
Atomic orbital is characterised by the quantum numbers and only.
🧠 Quantum vs. Classical Audit Bohr's model was a bridge between classical views (circular paths) and quantum mechanics (wave functions). We need to spot the one statement that oversimplifies the modern orbital definition.
🗺️ The Conceptual Filter
- Statement (1): Bohr did indeed propose the "circular path" planetary model. Correct.
- Statement (2): Technically, an orbital describes the spatial domain of a single electron's wave function (). Correct.
- Statement (3): The distinct lines of the H-spectrum were the exact proof Bohr used for quantized orbits. Correct.
- Statement (4): Says an orbital is characterized by and only.
- The Flaw: An atomic orbital requires three quantum numbers to define its shape and orientation: and . Missing makes the description incomplete. Incorrect.
⚡ The "Three vs. Two" Rule Remember the hierarchy:
- Shell (1 quantum number)
- Subshell (2 quantum numbers)
- Orbital (3 quantum numbers)
- Electron (4 quantum numbers) Seeing "orbital" and "only and " is an immediate conceptual mismatch.
⚠️ Common Traps Don't confuse "orbital" with "subshell." A subshell (like 2p) is indeed defined by and . But the orbital (like ) needs . Read the subject of the sentence carefully!
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