JEE Main · 2022 · Shift-IeasyATOM-051

Identify the incorrect statement from the following:

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

Identify the incorrect statement from the following:

Options
  1. a

    A circular path around the nucleus in which an electron moves is proposed as Bohr's orbit.

  2. b

    An orbital is the one electron wave function.

  3. c

    The existence of Bohr's orbits is supported by hydrogen spectrum.

  4. d

    Atomic orbital is characterised by the quantum numbers nn and ll only.

Correct Answerd

Atomic orbital is characterised by the quantum numbers nn and ll only.

Detailed Solution

🧠 Quantum vs. Classical Audit Bohr's model was a bridge between classical views (circular paths) and quantum mechanics (wave functions). We need to spot the one statement that oversimplifies the modern orbital definition.

🗺️ The Conceptual Filter

  • Statement (1): Bohr did indeed propose the "circular path" planetary model. Correct.
  • Statement (2): Technically, an orbital describes the spatial domain of a single electron's wave function (ψ\psi). Correct.
  • Statement (3): The distinct lines of the H-spectrum were the exact proof Bohr used for quantized orbits. Correct.
  • Statement (4): Says an orbital is characterized by nn and ll only.
    • The Flaw: An atomic orbital requires three quantum numbers to define its shape and orientation: n,l,n, l, and mlm_l. Missing mlm_l makes the description incomplete. Incorrect.

The "Three vs. Two" Rule Remember the hierarchy:

  • Shell     n\implies n (1 quantum number)
  • Subshell     n,l\implies n, l (2 quantum numbers)
  • Orbital     n,l,ml\implies n, l, m_l (3 quantum numbers)
  • Electron     n,l,ml,s\implies n, l, m_l, s (4 quantum numbers) Seeing "orbital" and "only nn and ll" is an immediate conceptual mismatch.

⚠️ Common Traps Don't confuse "orbital" with "subshell." A subshell (like 2p) is indeed defined by nn and ll. But the orbital (like 2pz2p_z) needs mlm_l. Read the subject of the sentence carefully!

Answer: (d)\boxed{\text{Answer: (d)}}

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