JEE Main · 2025 · Shift-ImediumATOM-210

If a0 is denoted as the Bohr radius of hydrogen atom, then what is the de-Broglie wavelength () of the electron present…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

If a0a_0 is denoted as the Bohr radius of hydrogen atom, then what is the de-Broglie wavelength (λ\lambda) of the electron present in the second orbit of hydrogen atom? [nn: any integer]

Options
  1. a

    2a0nπ\dfrac{2a_0}{n\pi}

  2. b

    8πa0n\dfrac{8\pi a_0}{n}

  3. c

    4πa0n\dfrac{4\pi a_0}{n}

  4. d

    4nπa0\dfrac{4n}{\pi a_0}

Correct Answerb

8πa0n\dfrac{8\pi a_0}{n}

Detailed Solution

🧠 The Circumference Quantization Louis de Broglie justified Bohr's "magic" orbits by suggesting that electrons form standing waves. For a wave to "survive" in a circle, the total path length (circumference) must fit exactly an integral number of wavelengths. 2πr=nλ2\pi r = n\lambda

🗺️ Building the Wavelength

  1. Orbit (nn): We are in the n=2n=2 orbit.
  2. Radius (rr): From Bohr theory, rn=a0n2r_n = a_0 n^2. For n=2n=2: r2=a0(2)2=4a0r_2 = a_0 (2)^2 = 4a_0.
  3. Equating for λ\lambda: 2πr2=2λ2\pi r_2 = 2 \lambda 2π(4a0)=2λ    8πa0=2λ2\pi (4a_0) = 2\lambda \implies 8\pi a_0 = 2\lambda λ=4πa0\lambda = 4\pi a_0
  4. Matching the Formula: The options use the general form λ=8πa0n\lambda = \frac{8\pi a_0}{n}. If we substitute n=2n=2 here, we get 8πa02=4πa0\frac{8\pi a_0}{2} = 4\pi a_0.

The 2πa0n2\pi a_0 n Shortcut For Hydrogen, the de-Broglie wavelength in any orbit nn is simply λn=2πa0n\lambda_n = 2\pi a_0 n. For n=2n=2, λ=4πa0\lambda = 4\pi a_0. Just find the option that simplifies to this!

⚠️ Radius vs. Circumference Don't say the wavelength is the radius. The wavelength is part of the length of the circle (2πr2\pi r). For the second orbit, two full wave-cycles must wrap around the nucleus.

Answer: (b)\boxed{\text{Answer: (b)}}

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