JEE Main · 2020 · Shift-ImediumATOM-090

The de Broglie wavelength of an electron in the 4th Bohr orbit is:

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

The de Broglie wavelength of an electron in the 4th4^{\text{th}} Bohr orbit is:

Options
  1. a

    2πa02\pi a_0

  2. b

    4πa04\pi a_0

  3. c

    6πa06\pi a_0

  4. d

    8πa08\pi a_0

Correct Answerd

8πa08\pi a_0

Detailed Solution

🧠 The Standing Wave Condition For an electron to exist in a stable Bohr orbit, the circumference of that orbit must precisely fit an integral number of de Broglie wavelengths (nλ=2πrn\lambda = 2\pi r). If it doesn't fit, the wave destroys itself through interference.

🗺️ The Wave Fit Path

  1. The Quantization Rule: nλ=2πrnn\lambda = 2\pi r_n For the 4th4^{\text{th}} orbit (n=4n=4): 4λ=2πr4    λ=πr424\lambda = 2\pi r_4 \implies \lambda = \frac{\pi r_4}{2}
  2. The Radius Scaling: In Hydrogen, rn=a0n2r_n = a_0 n^2. For n=4n=4: r4=a0(4)2=16a0r_4 = a_0 (4)^2 = 16 a_0
  3. The Final Substitution: λ=π(16a0)2=8πa0\lambda = \frac{\pi (16 a_0)}{2} = 8\pi a_0

The 2nπa02n\pi a_0 Shortcut Remember that since 2π(a0n2)=nλ2\pi (a_0 n^2) = n\lambda, the wavelength is simply 2πna02\pi n a_0. For n=4n=4, it's 8πa08\pi a_0. For n=3n=3, it's 6πa06\pi a_0.

⚠️ Common Traps Don't use the simple nλn\lambda product without accounting for the n2n^2 growth of the radius. The orbit gets much bigger as nn increases!

Answer: (d)\boxed{\text{Answer: (d)}}

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