JEE Main · 2020 · Shift-IIhardATOM-065

The shortest wavelength of H atom in the Lyman series is 1. The longest wavelength in the Balmer series of He+ is:

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

The shortest wavelength of H atom in the Lyman series is λ1\lambda_1. The longest wavelength in the Balmer series of He+\mathrm{He^+} is:

Options
  1. a

    36λ15\frac{36\lambda_1}{5}

  2. b

    5λ19\frac{5\lambda_1}{9}

  3. c

    9λ15\frac{9\lambda_1}{5}

  4. d

    27λ15\frac{27\lambda_1}{5}

Correct Answerc

9λ15\frac{9\lambda_1}{5}

Detailed Solution

🧠 The Scaling Identity This is a conceptual twin to ATOM-062. We are comparing the "series limit" of Hydrogen's ground state against the "first line" of Helium's second series. Because Z=2Z=2 for Helium, it exactly cancels out the energy drop of moving to n=2n=2, keeping the wavelengths in the same order of magnitude.

🗺️ The Derivation Map

  1. Lyman Shortest (H): Transition 1\infty \to 1. 1λ1=R(1)2(1120)    R=1λ1\frac{1}{\lambda_1} = R(1)^2 \left( \frac{1}{1^2} - 0 \right) \implies R = \frac{1}{\lambda_1}
  2. Balmer Longest (\ceHe+\ce{He^+}): Transition 323 \to 2 with Z=2Z=2. 1λmax=R(2)2(122132)=4R(1419)=4R(536)\frac{1}{\lambda_{max}} = R(2)^2 \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = 4R \left( \frac{1}{4} - \frac{1}{9} \right) = 4R \left( \frac{5}{36} \right)
  3. Solving: 1λmax=5R9=59λ1    λmax=9λ15\frac{1}{\lambda_{max}} = \frac{5R}{9} = \frac{5}{9\lambda_1} \implies \lambda_{max} = \frac{9\lambda_1}{5}

The 9:5 Ratio If you memorize that the HαH_\alpha line factor is 5/365/36, and the Rydberg limit factor is 11, the rest is just algebra with Z2Z^2. For Helium, the Z2Z^2 is 44. 4×(5/36)=5/94 \times (5/36) = 5/9. Reciprocal factor =9/5= 9/5.

⚠️ Common Traps Be careful with the variable name! The question uses λ1\lambda_1. Don't let your eyes skip the subscript and pick a generic constant.

Answer: (C)\boxed{\text{Answer: (C)}}

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