JEE Main · 2019 · Shift-IhardTHERMO-062

Two blocks of same metal having same mass and at T1 and T2 , respectively, are brought in contact with each other and…

Thermodynamics · Class 11 · JEE Main Previous Year Question

Question

Two blocks of same metal having same mass and at T1T_1 and T2T_2 , respectively, are brought in contact with each other and allowed to reach thermal equilibrium at constant pressure. The change of entropy, ΔS\Delta S for the process is:

Options
  1. a

    CPln[(T1+T2)24T1T2]C_P\ln\left[\frac{(T_1+T_2)^2}{4T_1T_2}\right]

  2. b

    2CPln[(T1+T2)1/2T1T2]2C_P\ln\left[\frac{(T_1+T_2)^{1/2}}{T_1T_2}\right]

  3. c

    2CPln(T1+T24T1T2)2C_P\ln\left(\frac{T_1+T_2}{4T_1T_2}\right)

  4. d

    2CPln[T1+T22T1T2]2C_P\ln\left[\frac{T_1+T_2}{2T_1T_2}\right]

Correct Answera

CPln[(T1+T2)24T1T2]C_P\ln\left[\frac{(T_1+T_2)^2}{4T_1T_2}\right]

Detailed Solution

🧠 Thermal equilibrium at constant pressure: final temperature = average, entropy change = ln of a ratio When two equal masses reach equilibrium: Tf=(T1+T2)/2T_f = (T_1 + T_2)/2. Each block's entropy change is CPln(Tf/Ti)C_P \ln(T_f / T_i).

🗺️ Calculation Final temperature by heat balance (equal masses, same metal, constant pressure): Tf=T1+T22T_f = \frac{T_1 + T_2}{2}

Entropy change of block 1: ΔS1=CPlnTfT1=CPlnT1+T22T1\Delta S_1 = C_P \ln\frac{T_f}{T_1} = C_P \ln\frac{T_1+T_2}{2T_1}

Entropy change of block 2: ΔS2=CPlnTfT2=CPlnT1+T22T2\Delta S_2 = C_P \ln\frac{T_f}{T_2} = C_P \ln\frac{T_1+T_2}{2T_2}

Total entropy change: ΔS=ΔS1+ΔS2=CP[lnT1+T22T1+lnT1+T22T2]\Delta S = \Delta S_1 + \Delta S_2 = C_P \left[\ln\frac{T_1+T_2}{2T_1} + \ln\frac{T_1+T_2}{2T_2}\right] =CPln(T1+T2)24T1T2= C_P \ln\frac{(T_1+T_2)^2}{4T_1 T_2}

⚠️ Trap: Don't write 2CPln[]2C_P \ln[\ldots] — it's CPC_P (not 2CP2C_P) because each block contributes one term that combines as a product inside a single logarithm.

Answer: (a)\boxed{\text{Answer: (a)}}

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