The correct IUPAC name of K2MnO4 is:
Coordination Compounds · Class 12 · JEE Main Previous Year Question
The correct IUPAC name of is:
- a
Potassium tetraoxopermanganate(VI)
- b✓
Potassium tetraoxidomanganate(VI)
- c
Dipotassium tetraoxidomanganate(VII)
- d
Potassium tetraoxidomanganese(VI)
Potassium tetraoxidomanganate(VI)
🧠 Three IUPAC Updates Hidden Here
JEE 2024 names test the modern (post-2005) IUPAC conventions:
- Oxide ligand is now "oxido", not "oxo".
- Inside an anionic complex the metal still ends in -ate, but the metal stem is the standard name (manganate, not manganese).
- The cation count ("dipotassium") is omitted in IUPAC names — only the metal's charge state matters.
🗺️ Build the Name
The species is — manganate(VI), four oxide ligands.
Oxidation state of Mn. .
Ligand block. 4 × oxide → "tetraoxido".
Metal block. Anionic complex → "manganate", with (VI) appended.
Cation block. "Potassium" — no "di" prefix in modern IUPAC.
Stitch: Potassium tetraoxidomanganate(VI).
⚡ Three-Word Pattern
Anionic complex names always read: cation + ligand-prefix-metal + (oxidation state). For oxoanions: → potassium tetraoxidochromate(VI), → potassium tetraoxidomanganate(VII).
⚠️ "Dipotassium" Is Wrong
Option (3) prefixes potassium with "di" — old style. Modern IUPAC drops cation multipliers because the formula already encodes them. Likewise, "permanganate" (option 1) is a common name, not an IUPAC name.
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