The correct IUPAC name of [Ni(CO)4] is:
Coordination Compounds · Class 12 · JEE Main Previous Year Question
The correct IUPAC name of is:
- a
Nickel tetracarbonyl
- b✓
Tetracarbonylnickel(0)
- c
Tetracarbonylnickelate(0)
- d
Tetracarbonylnickel
Tetracarbonylnickel(0)
🧠 Zero Counts as a Number
Tetracarbonyl nickel is the textbook neutral metal-carbonyl. Two things make it a frequent JEE option-trap:
- The metal oxidation state is 0, and in IUPAC names you must write that 0 explicitly: "nickel**(0)**".
- The complex is neutral, not anionic — so the metal name stays "nickel", not "nickelate".
🗺️ Build the Name
Ligand block. 4 × carbonyl → "tetracarbonyl". (CO is treated as a simple ligand → "tetra-", not "tetrakis-".)
Oxidation state. has zero charge; is neutral; the entire complex is neutral. So is in oxidation state 0.
Metal block. Neutral complex → "nickel", with (0) appended.
Stitched: tetracarbonylnickel(0) — option (2).
⚡ The "(0) Always Stated" Rule
Even when the metal's oxidation state is zero, IUPAC requires the Roman-numeral parenthesis. Options that drop the (0) — like option (4) "Tetracarbonylnickel" — are wrong on a technicality but a deliberate one.
⚠️ Common Name vs IUPAC
"Nickel tetracarbonyl" (option 1) is the traditional name still used in industry. IUPAC convention puts the ligand block first, then the metal — so "tetracarbonylnickel(0)" is correct, "nickel tetracarbonyl" is not. Likewise, "tetracarbonylnickelate(0)" (option 3) is wrong because the complex is neutral, not anionic.
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