JEE Main · 2022 · Shift-ImediumDNF-013

Among the following, which is the strongest oxidizing agent?

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

Among the following, which is the strongest oxidizing agent?

Options
  1. a

    Mn3+\text{Mn}^{3+}

  2. b

    Ti3+\text{Ti}^{3+}

  3. c

    Fe3+\text{Fe}^{3+}

  4. d

    Cr3+\text{Cr}^{3+}

Correct Answera

Mn3+\text{Mn}^{3+}

Detailed Solution

Concept: E°M3+/M2+E°_{M^{3+}/M^{2+}} — higher value = stronger oxidising agent

| Ion | E°M3+/M2+E°_{M^{3+}/M^{2+}} (V) | Reason | |-----|--------------------------|--------| | Mn3+\text{Mn}^{3+} | +1.57+1.57 | Product Mn2+\text{Mn}^{2+} (3d53d^5, half-filled) is extra stable | | Fe3+\text{Fe}^{3+} | +0.77+0.77 | Moderate | | Ti3+\text{Ti}^{3+} | 0.37-0.37 | Poor oxidiser | | Cr3+\text{Cr}^{3+} | 0.41-0.41 | Cr3+\text{Cr}^{3+} (3d33d^3) is very stable, poor oxidiser |

Mn3+\text{Mn}^{3+} is the strongest oxidising agent because Mn2+\text{Mn}^{2+} (the reduction product) has the extra-stable half-filled 3d53d^5 configuration.

Answer: Option (1) — Mn3+\text{Mn}^{3+}

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