JEE Main · 2019 · Shift-IImediumHC-021

Which of these factors does not govern the stability of a conformation in acyclic compounds?

Hydrocarbons · Class 11 · JEE Main Previous Year Question

Question

Which of these factors does not govern the stability of a conformation in acyclic compounds?

Options
  1. a

    Torsional strain

  2. b

    Angle strain

  3. c

    Steric interactions

  4. d

    Electrostatic forces of interaction

Correct Answerb

Angle strain

Detailed Solution

Step 1: Understand what governs conformational stability in acyclic compounds For open-chain (acyclic) compounds, the main factors affecting conformational stability are:

  1. Torsional strain — energy due to eclipsing of bonds; staggered conformations have less torsional strain
  2. Steric interactions — repulsion between bulky groups when they are close in space (e.g., gauche interactions)
  3. Electrostatic forces — attractive or repulsive interactions between polar groups

image Step 2: Evaluate angle strain Angle strain arises when bond angles deviate from their ideal values (e.g., 109.5° for sp3sp^3 C). This is a property of ring systems (cyclopropane, cyclobutane), NOT of acyclic compounds.

In acyclic compounds, bond angles freely adopt their optimal values — there is no angle strain in conformational analysis of open-chain molecules.

Step 3: Identify the answer The factor that does NOT govern conformational stability in acyclic compounds is Angle strainOption (b)

Key Points to Remember:

  • Angle strain = a ring property (cycloalkanes), NOT a conformational property
  • Torsional strain, steric interactions, and electrostatics all affect acyclic conformations
  • Cyclopropane has maximum angle strain (60° vs ideal 109.5°)

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