Which of these factors does not govern the stability of a conformation in acyclic compounds?
Hydrocarbons · Class 11 · JEE Main Previous Year Question
Which of these factors does not govern the stability of a conformation in acyclic compounds?
- a
Torsional strain
- b✓
Angle strain
- c
Steric interactions
- d
Electrostatic forces of interaction
Angle strain
Step 1: Understand what governs conformational stability in acyclic compounds For open-chain (acyclic) compounds, the main factors affecting conformational stability are:
- Torsional strain — energy due to eclipsing of bonds; staggered conformations have less torsional strain
- Steric interactions — repulsion between bulky groups when they are close in space (e.g., gauche interactions)
- Electrostatic forces — attractive or repulsive interactions between polar groups
Step 2: Evaluate angle strain
Angle strain arises when bond angles deviate from their ideal values (e.g., 109.5° for C). This is a property of ring systems (cyclopropane, cyclobutane), NOT of acyclic compounds.
In acyclic compounds, bond angles freely adopt their optimal values — there is no angle strain in conformational analysis of open-chain molecules.
Step 3: Identify the answer The factor that does NOT govern conformational stability in acyclic compounds is Angle strain → Option (b)
Key Points to Remember:
- Angle strain = a ring property (cycloalkanes), NOT a conformational property
- Torsional strain, steric interactions, and electrostatics all affect acyclic conformations
- Cyclopropane has maximum angle strain (60° vs ideal 109.5°)
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