JEE Main · 2021 · Shift-ImediumRDX-007

(A) HOCl + H2O2 H3O+ + Cl- + O2 (B) I2 + H2O2 + 2OH- 2I- + 2H2O + O2 Choose the correct option:

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

(A) HOCl+H2O2H3O++Cl+O2\mathrm{HOCl + H_2O_2 \rightarrow H_3O^{+} + Cl^{-} + O_2} (B) I2+H2O2+2OH2I+2H2O+O2\mathrm{I_2 + H_2O_2 + 2OH^{-} \rightarrow 2I^{-} + 2H_2O + O_2}

Choose the correct option:

Options
  1. a

    H2O2\mathrm{H_2O_2} acts as oxidizing and reducing agent respectively in equations (A) and (B).

  2. b

    H2O2\mathrm{H_2O_2} acts as oxidising agent in equations (A) and (B).

  3. c

    H2O2\mathrm{H_2O_2} acts as reducing and oxidising agent respectively in equations (A) and (B).

  4. d

    H2O2\mathrm{H_2O_2} acts as reducing agent in equations (A) and (B).

Correct Answerd

H2O2\mathrm{H_2O_2} acts as reducing agent in equations (A) and (B).

Detailed Solution

Step 1 — Analyse reaction (A): HOCl+H2O2H3O++Cl+O2\mathrm{HOCl + H_2O_2 \rightarrow H_3O^{+} + Cl^{-} + O_2}

  • In H2O2\mathrm{H_2O_2}: O is 1-1

  • In O2\mathrm{O_2} (product): O is 00

  • O goes from 10-1 \rightarrow 0: oxidation (loss of electrons)

  • H2O2\mathrm{H_2O_2} is oxidised → acts as reducing agent in (A)

  • In HOCl\mathrm{HOCl}: Cl is +1+1; in Cl\mathrm{Cl^-}: Cl is 1-1 → Cl is reduced → HOCl is the oxidizing agent

Step 2 — Analyse reaction (B): I2+H2O2+2OH2I+2H2O+O2\mathrm{I_2 + H_2O_2 + 2OH^{-} \rightarrow 2I^{-} + 2H_2O + O_2}

  • In H2O2\mathrm{H_2O_2}: O is 1-1

  • In O2\mathrm{O_2}: O is 00

  • O goes from 10-1 \rightarrow 0: oxidation

  • H2O2\mathrm{H_2O_2} is oxidised → acts as reducing agent in (B)

  • I2\mathrm{I_2} (0) → I\mathrm{I^-} (1-1): reduced → I2\mathrm{I_2} is the oxidizing agent

Conclusion: H2O2\mathrm{H_2O_2} acts as reducing agent in BOTH (A) and (B)

Answer: Option (4)

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Redox Reactions) inside The Crucible, our adaptive practice platform.