JEE Main · 2021 · Shift-ImediumRDX-007

(A) HOCl + H2O2 H3O+ + Cl- + O2 (B) I2 + H2O2 + 2OH- 2I- + 2H2O + O2 Choose the correct option:

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

(A) HOCl+H2O2H3O++Cl+O2\mathrm{HOCl + H_2O_2 \rightarrow H_3O^{+} + Cl^{-} + O_2} (B) I2+H2O2+2OH2I+2H2O+O2\mathrm{I_2 + H_2O_2 + 2OH^{-} \rightarrow 2I^{-} + 2H_2O + O_2}

Choose the correct option:

Options
  1. a

    H2O2\mathrm{H_2O_2} acts as oxidizing and reducing agent respectively in equations (A) and (B).

  2. b

    H2O2\mathrm{H_2O_2} acts as oxidising agent in equations (A) and (B).

  3. c

    H2O2\mathrm{H_2O_2} acts as reducing and oxidising agent respectively in equations (A) and (B).

  4. d

    H2O2\mathrm{H_2O_2} acts as reducing agent in equations (A) and (B).

Correct Answerd

H2O2\mathrm{H_2O_2} acts as reducing agent in equations (A) and (B).

Detailed Solution

Step 1 — Analyse reaction (A): HOCl+H2O2H3O++Cl+O2\mathrm{HOCl + H_2O_2 \rightarrow H_3O^{+} + Cl^{-} + O_2}

  • In H2O2\mathrm{H_2O_2}: O is 1-1

  • In O2\mathrm{O_2} (product): O is 00

  • O goes from 10-1 \rightarrow 0: oxidation (loss of electrons)

  • H2O2\mathrm{H_2O_2} is oxidised → acts as reducing agent in (A)

  • In HOCl\mathrm{HOCl}: Cl is +1+1; in Cl\mathrm{Cl^-}: Cl is 1-1 → Cl is reduced → HOCl is the oxidizing agent

Step 2 — Analyse reaction (B): I2+H2O2+2OH2I+2H2O+O2\mathrm{I_2 + H_2O_2 + 2OH^{-} \rightarrow 2I^{-} + 2H_2O + O_2}

  • In H2O2\mathrm{H_2O_2}: O is 1-1

  • In O2\mathrm{O_2}: O is 00

  • O goes from 10-1 \rightarrow 0: oxidation

  • H2O2\mathrm{H_2O_2} is oxidised → acts as reducing agent in (B)

  • I2\mathrm{I_2} (0) → I\mathrm{I^-} (1-1): reduced → I2\mathrm{I_2} is the oxidizing agent

Conclusion: H2O2\mathrm{H_2O_2} acts as reducing agent in BOTH (A) and (B)

Answer: Option (4)

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Redox Reactions) inside The Crucible, our adaptive practice platform.

(A) HOCl + H2O2 H3O+ + Cl- + O2 (B) I2 + H2O2 + 2OH- 2I- + 2H2O + O2 Choose the correct option: (JEE Main 2021) | Canvas Classes