JEE Main · 2023 · Shift-ImediumRDX-005

Strong reducing and oxidizing agents among the following, respectively, are

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

Strong reducing and oxidizing agents among the following, respectively, are

Options
  1. a

    Ce3+\mathrm{Ce^{3+}} and Ce4+\mathrm{Ce^{4+}}

  2. b

    Ce4+\mathrm{Ce^{4+}} and Tb4+\mathrm{Tb^{4+}}

  3. c

    Ce4+\mathrm{Ce^{4+}} and Eu2+\mathrm{Eu^{2+}}

  4. d

    Eu2+\mathrm{Eu^{2+}} and Ce4+\mathrm{Ce^{4+}}

Correct Answerd

Eu2+\mathrm{Eu^{2+}} and Ce4+\mathrm{Ce^{4+}}

Detailed Solution

Step 1 — Identify strong reducing agents (easily oxidised):

  • Eu2+\mathrm{Eu^{2+}}: Europium prefers the +3 state (stable 4f74f^7 configuration at +3). Eu2+\mathrm{Eu^{2+}} (4f74f^7) is very stable but readily loses an electron to reach Eu3+\mathrm{Eu^{3+}} (4f64f^6)...

Actually, Eu2+\mathrm{Eu^{2+}} has 4f74f^7 (half-filled, stable), but it is a strong reducing agent because it can donate electrons to reach Eu3+\mathrm{Eu^{3+}}.

  • Ce3+\mathrm{Ce^{3+}}: Stable configuration; poor reducing agent.

Step 2 — Identify strong oxidizing agents (easily reduced):

  • Ce4+\mathrm{Ce^{4+}}: Ce prefers +3 state (empty 4f4f shell at +4 is less stable). Ce4+\mathrm{Ce^{4+}} readily accepts an electron to become Ce3+\mathrm{Ce^{3+}} (stable 4f04f^0) → strong oxidizing agent
  • Tb4+\mathrm{Tb^{4+}}: Less common; Ce4+\mathrm{Ce^{4+}} is the classic strong oxidizer among lanthanides.

Step 3 — Conclusion:

  • Strong reducing agent: Eu2+\mathrm{Eu^{2+}} (donates ee^- easily)
  • Strong oxidizing agent: Ce4+\mathrm{Ce^{4+}} (accepts ee^- easily)

Answer: Option (4) — Eu2+\mathrm{Eu^{2+}} and Ce4+\mathrm{Ce^{4+}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Redox Reactions) inside The Crucible, our adaptive practice platform.

Strong reducing and oxidizing agents among the following, respectively, are (JEE Main 2023) | Canvas Classes