JEE Main · 2023 · Shift-ImediumRDX-005

Strong reducing and oxidizing agents among the following, respectively, are

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

Strong reducing and oxidizing agents among the following, respectively, are

Options
  1. a

    Ce3+\mathrm{Ce^{3+}} and Ce4+\mathrm{Ce^{4+}}

  2. b

    Ce4+\mathrm{Ce^{4+}} and Tb4+\mathrm{Tb^{4+}}

  3. c

    Ce4+\mathrm{Ce^{4+}} and Eu2+\mathrm{Eu^{2+}}

  4. d

    Eu2+\mathrm{Eu^{2+}} and Ce4+\mathrm{Ce^{4+}}

Correct Answerd

Eu2+\mathrm{Eu^{2+}} and Ce4+\mathrm{Ce^{4+}}

Detailed Solution

Step 1 — Identify strong reducing agents (easily oxidised):

  • Eu2+\mathrm{Eu^{2+}}: Europium prefers the +3 state (stable 4f74f^7 configuration at +3). Eu2+\mathrm{Eu^{2+}} (4f74f^7) is very stable but readily loses an electron to reach Eu3+\mathrm{Eu^{3+}} (4f64f^6)...

Actually, Eu2+\mathrm{Eu^{2+}} has 4f74f^7 (half-filled, stable), but it is a strong reducing agent because it can donate electrons to reach Eu3+\mathrm{Eu^{3+}}.

  • Ce3+\mathrm{Ce^{3+}}: Stable configuration; poor reducing agent.

Step 2 — Identify strong oxidizing agents (easily reduced):

  • Ce4+\mathrm{Ce^{4+}}: Ce prefers +3 state (empty 4f4f shell at +4 is less stable). Ce4+\mathrm{Ce^{4+}} readily accepts an electron to become Ce3+\mathrm{Ce^{3+}} (stable 4f04f^0) → strong oxidizing agent
  • Tb4+\mathrm{Tb^{4+}}: Less common; Ce4+\mathrm{Ce^{4+}} is the classic strong oxidizer among lanthanides.

Step 3 — Conclusion:

  • Strong reducing agent: Eu2+\mathrm{Eu^{2+}} (donates ee^- easily)
  • Strong oxidizing agent: Ce4+\mathrm{Ce^{4+}} (accepts ee^- easily)

Answer: Option (4) — Eu2+\mathrm{Eu^{2+}} and Ce4+\mathrm{Ce^{4+}}

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