JEE Main · 2020 · Shift-IeasyRDX-028

Oxidation number of potassium in K2O, K2O2 and KO2, respectively, is:

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

Oxidation number of potassium in K2O\mathrm{K_2O}, K2O2\mathrm{K_2O_2} and KO2\mathrm{KO_2}, respectively, is:

Options
  1. a

    +2,+1+2, +1 and +12+\frac{1}{2}

  2. b

    +1,+1+1, +1 and +1+1

  3. c

    +1,+4+1, +4 and +2+2

  4. d

    +1,+2+1, +2 and +4+4

Correct Answerb

+1,+1+1, +1 and +1+1

Detailed Solution

Key rule: Potassium is an alkali metal and always has oxidation state +1 in its compounds.

Step 1 — K2O\mathrm{K_2O} (potassium oxide): 2(+1)+x=0xO=22(+1) + x = 0 \Rightarrow x_{\mathrm{O}} = -2 K = +1 ✓ (O is 2-2, normal oxide)

Step 2 — K2O2\mathrm{K_2O_2} (potassium peroxide): 2(+1)+2x=0xO=12(+1) + 2x = 0 \Rightarrow x_{\mathrm{O}} = -1 K = +1 ✓ (O is 1-1, peroxide)

Step 3 — KO2\mathrm{KO_2} (potassium superoxide): (+1)+2x=0xO=12(+1) + 2x = 0 \Rightarrow x_{\mathrm{O}} = -\frac{1}{2} K = +1 ✓ (O is 12-\frac{1}{2}, superoxide)

Note: The oxidation state of O changes (+2, -1, -½) but K remains +1 throughout.

Answer: Option (2) — +1, +1 and +1

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