JEE Main · 2019 · Shift-IIhardATOM-095

If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to 1.5 a0 (a0 is Bohr…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

If the de Broglie wavelength of the electron in nthn^{\text{th}} Bohr orbit in a hydrogenic atom is equal to 1.5πa01.5\pi a_0 (a0a_0 is Bohr radius), then the value of n/zn/z is:

Options
  1. a

    1.50

  2. b

    1.0

  3. c

    0.4

  4. d

    0.75

Correct Answerd

0.75

Detailed Solution

🧠 The Orbit Circumference According to Bohr and de Broglie, for an orbit to be stable, the path taken (2πr2\pi r) must be an exact multiple of the electron's wavelength.

🗺️ The Geometric Equation

  1. The Core Law: nλ=2πrnn\lambda = 2\pi r_n.
  2. The Bohr Radius: rn=a0n2Zr_n = a_0 \frac{n^2}{Z}.
  3. Plugging into the Wave Condition: n(1.5πa0)=2π(a0n2Z)n (1.5\pi a_0) = 2\pi \left( a_0 \frac{n^2}{Z} \right)
  4. Simplifying: Cancel π,a0,\pi, a_0, and one nn: 1.5=2nZ1.5 = 2 \frac{n}{Z} nZ=1.52=0.75\frac{n}{Z} = \frac{1.5}{2} = 0.75

The 1.5/21.5/2 Quick Fix The ratio n/Zn/Z is essentially a measurement of how "stretched" the wavelength is relative to the radius. Since 2πr2\pi r is 2×2\times the radius factor, the result is simply half of the 1.51.5 coefficient.

⚠️ Common Traps Forgetting that rnr_n scales with n2n^2. If you use rn=a0n/Zr_n = a_0 n/Z, you will get an incorrect value of 1.5cdot21.5 cdot 2.

Answer: (d)\boxed{\text{Answer: (d)}}

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