JEE Main · 2021 · Shift-IeasyBOND-083

A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this molecule is

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this molecule is

Options
  1. a

    See-saw

  2. b

    Planar triangular

  3. c

    T-shaped

  4. d

    Trigonal pyramidal

Correct Answerc

T-shaped

Detailed Solution

🧠 Count total electron groups: 3 single bonds + 2 lone pairs = steric number 5 → trigonal bipyramidal electron geometry. The 2 lone pairs occupy the equatorial positions (lowest repulsion), leaving the 3 bond pairs in a T arrangement.

Molecular shape = T-shaped (2 axial bonds + 1 equatorial bond, with 2 LP in the equatorial plane).

⚠️ Trap: Trigonal pyramidal (option d) requires 3 bonds + 1 LP (steric number 4). Here there are 2 LP, not 1. See-saw requires 4 bonds + 1 LP (steric number 5 but different LP count).

Answer: (c) T-shaped\boxed{\text{Answer: (c) T-shaped}}

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