JEE Main · 2024 · Shift-IIeasyBOND-140

Given below are two statements — Assertion A and Reason R: Assertion A: H2Te is more acidic than H2S. Reason R: Bond…

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

Given below are two statements — Assertion A and Reason R:

Assertion A: H2Te\mathrm{H_2Te} is more acidic than H2S\mathrm{H_2S}.

Reason R: Bond dissociation enthalpy of H2Te\mathrm{H_2Te} is lower than H2S\mathrm{H_2S}.

Choose the most appropriate answer:

Options
  1. a

    Both A and R are true but R is NOT the correct explanation of A

  2. b

    Both A and R are true and R is the correct explanation of A

  3. c

    A is false but R is true

  4. d

    A is true but R is false

Correct Answerb

Both A and R are true and R is the correct explanation of A

Detailed Solution

🧠 Acidity of group 16 hydrides depends primarily on bond dissociation enthalpy (not electronegativity), since weaker bonds release H⁺ more easily.

🗺️ Evaluate Assertion A:

Acidity order of group 16 hydrides (down the group): H2O<H2S<H2Se<H2Te\mathrm{H_2O < H_2S < H_2Se < H_2Te}

H2Te\mathrm{H_2Te} is more acidic than H2S\mathrm{H_2S}A is TRUE

Evaluate Reason R:

Bond dissociation enthalpies: H–O > H–S > H–Se > H–Te (bond strength decreases as the central atom gets larger and its orbital overlaps with H decreases).

Weaker H–Te bond → H is released more easily → higher acidity of H2Te\mathrm{H_2Te} compared to H2S\mathrm{H_2S}.

R is TRUE ✓ and R correctly explains A

⚠️ Common trap: students think electronegativity (O > S > Se > Te) should make H2O\mathrm{H_2O} the most acidic. But in aqueous phase, bond strength dominates — the H–Te bond is so weak that H2Te\mathrm{H_2Te} ionizes far more readily.

Answer: Both A and R are true and R is the correct explanation\boxed{\text{Answer: Both A and R are true and R is the correct explanation}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Chemical Bonding) inside The Crucible, our adaptive practice platform.