Given below are two statements — Assertion A and Reason R: Assertion A: H2Te is more acidic than H2S. Reason R: Bond…
Chemical Bonding · Class 11 · JEE Main Previous Year Question
Given below are two statements — Assertion A and Reason R:
Assertion A: is more acidic than .
Reason R: Bond dissociation enthalpy of is lower than .
Choose the most appropriate answer:
- a
Both A and R are true but R is NOT the correct explanation of A
- b✓
Both A and R are true and R is the correct explanation of A
- c
A is false but R is true
- d
A is true but R is false
Both A and R are true and R is the correct explanation of A
🧠 Acidity of group 16 hydrides depends primarily on bond dissociation enthalpy (not electronegativity), since weaker bonds release H⁺ more easily.
🗺️ Evaluate Assertion A:
Acidity order of group 16 hydrides (down the group):
is more acidic than → A is TRUE ✓
Evaluate Reason R:
Bond dissociation enthalpies: H–O > H–S > H–Se > H–Te (bond strength decreases as the central atom gets larger and its orbital overlaps with H decreases).
Weaker H–Te bond → H is released more easily → higher acidity of compared to .
R is TRUE ✓ and R correctly explains A ✓
⚠️ Common trap: students think electronegativity (O > S > Se > Te) should make the most acidic. But in aqueous phase, bond strength dominates — the H–Te bond is so weak that ionizes far more readily.
Practice this question with progress tracking
Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Chemical Bonding) inside The Crucible, our adaptive practice platform.
More JEE Main Chemical Bonding PYQs
A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A, X and Y.…
Among SO2, NF3, NH3, XeF2, ClF3 and SF4, the hybridization of the molecule with non-zero dipole moment and highest number of lone pairs of electrons on the central atom is:
Which among the following molecules is (a) involved in sp3d hybridization, (b) has different bond lengths and (c) has lone pair of electrons on the central atom?
Consider 'n' is the number of lone pair of electrons present in the equatorial position of the most stable structure of ClF3. The ions from the following with 'n' number of unpaired electrons are:…
The molecules having square pyramidal geometry are: