If the boiling point of H2O is 373 K, the boiling point of H2S will be:
Chemical Bonding · Class 11 · JEE Main Previous Year Question
If the boiling point of is 373 K, the boiling point of will be:
- a✓
Less than 300 K
- b
Equal to 373 K
- c
More than 373 K
- d
Greater than 300 K but less than 373 K
Less than 300 K
🧠 Compare and : water's high boiling point (373 K) is due to extensive hydrogen bonding. Sulfur is not electronegative enough to support H-bonding.
🗺️ Key difference:
- : O is highly electronegative → strong O–H···O H-bonds → high bp = 373 K
- : S is not electronegative enough → no H-bonding → only weak van der Waals forces hold molecules together
Expected boiling point of :
Without H-bonding, relies on dispersion forces only. bp() ≈ 213 K (−60 °C), which is significantly below 300 K.
⚡ The anomalously high bp of compared to , , and is direct evidence of hydrogen bonding.
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