Number of lone pair(s) of electrons on central atom and the shape of BrF3 molecule respectively, are:
Chemical Bonding · Class 11 · JEE Main Previous Year Question
Number of lone pair(s) of electrons on central atom and the shape of molecule respectively, are:
- a
0, triangular planar
- b
1, pyramidal
- c✓
2, bent T-shape
- d
1, bent T-shape
2, bent T-shape
🧠 : Br is in period 4 with 7 valence electrons. After forming 3 bonds to F, 4 electrons remain on Br → 2 lone pairs. Total steric number = 3 bonds + 2 LP = 5 → trigonal bipyramidal electron geometry. The 2 lone pairs occupy the equatorial positions (largest space) → T-shaped (bent T-shape) molecular geometry.
🗺️ Lone pairs occupy equatorial > axial in trigonal bipyramidal because equatorial lone pairs have only 2 axial neighbours at 90°, while axial lone pairs would have 3 equatorial neighbours at 90°.
⚠️ Trap: Option (d) says 1 lone pair → T-shape. That's wrong on the LP count. has 2 lone pairs, and still gives T-shape — option (c) is the only one correct on both counts.
Practice this question with progress tracking
Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Chemical Bonding) inside The Crucible, our adaptive practice platform.
More JEE Main Chemical Bonding PYQs
A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A, X and Y.…
Among SO2, NF3, NH3, XeF2, ClF3 and SF4, the hybridization of the molecule with non-zero dipole moment and highest number of lone pairs of electrons on the central atom is:
Which among the following molecules is (a) involved in sp3d hybridization, (b) has different bond lengths and (c) has lone pair of electrons on the central atom?
Consider 'n' is the number of lone pair of electrons present in the equatorial position of the most stable structure of ClF3. The ions from the following with 'n' number of unpaired electrons are:…
The molecules having square pyramidal geometry are: