JEE Main · 2020 · Shift-IeasyBOND-150

The relative strength of the interionic/intermolecular forces in decreasing order is:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

The relative strength of the interionic/intermolecular forces in decreasing order is:

Options
  1. a

    Dipole–dipole > ion–dipole > ion–ion

  2. b

    Ion–dipole > ion–ion > dipole–dipole

  3. c

    Ion–dipole > dipole–dipole > ion–ion

  4. d

    Ion–ion > ion–dipole > dipole–dipole

Correct Answerd

Ion–ion > ion–dipole > dipole–dipole

Detailed Solution

🧠 The strength of interionic/intermolecular forces decreases as the charge/permanence of the interacting species decreases: ions interact more strongly than permanent dipoles, which interact more strongly than transient dipoles.

🗺️ Decreasing order of force strength:

| Force | Nature of Species | Relative Strength | |-------|------------------|------------------| | Ion–ion | Both species are full charges | Strongest | | Ion–dipole | One full charge, one permanent dipole | Intermediate | | Dipole–dipole | Both permanent dipoles | Weakest of these three |

Ion–ion>Ion–dipole>Dipole–dipole\text{Ion–ion} > \text{Ion–dipole} > \text{Dipole–dipole}

⚡ Note: London (dispersion) forces are generally the weakest of all intermolecular interactions, but they are not in this comparison. Among the three listed, ion–ion is always dominant.

Answer: Ion–ion>Ion–dipole>Dipole–dipole\boxed{\text{Answer: Ion–ion} > \text{Ion–dipole} > \text{Dipole–dipole}}

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