The correct IUPAC name of K2[PtCl4] is:
Coordination Compounds · Class 12 · JEE Main Previous Year Question
The correct IUPAC name of is:
- a
Potassium tetrachloroplatinate(II)
- b
Dipotassium tetrachloridoplatinate(II)
- c✓
Potassium tetrachloridoplatinate(II)
- d
Potassium tetrachloridoplatinum(II)
Potassium tetrachloridoplatinate(II)
🧠 Three Things at Once
tests three IUPAC reflexes simultaneously:
- The complex is anionic → metal name flips to "platinate" (-ate suffix).
- Outer cation is potassium → name as just "potassium", not "dipotassium" (modern convention drops the multiplier).
- "Chloro" or "chlorido"? Modern IUPAC uses "chlorido".
🗺️ Construct It
Ligand block. 4 × chlorido → "tetrachlorido".
Oxidation state of Pt. . So Pt(II).
Metal block. Anionic → "platinate(II)".
Counter-ion. Two outer K⁺ → "potassium" (no "di-").
Stitched: Potassium tetrachloridoplatinate(II) — option (3).
⚡ The Three-Filter Sweep
Running the three filters in order:
- "Tetrachloro" → reject (old convention) → kills option (1).
- "Dipotassium" → reject (multiplier on cation) → kills option (2).
- "Platinum" instead of "platinate" → reject (anionic complex needs -ate) → kills option (4).
What's left? Option (3).
⚠️ The "Platinum vs Platinate" Slip
Many students mechanically write the metal's regular name. For an anion, you must convert to the -ate form: platinum → platinate, ferrum → ferrate, cobalt → cobaltate. Forgetting this conversion is the classic single-mark-loser.
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