JEE Main · 2019 · Shift-IeasyDNF-028

The element that usually does NOT show variable oxidation states is:

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

The element that usually does NOT show variable oxidation states is:

Options
  1. a

    Cu

  2. b

    Ti

  3. c

    Sc

  4. d

    V

Correct Answerc

Sc

Detailed Solution

Variable oxidation states arise from availability of both 3d and 4s electrons.

| Element | Z | Config | Oxidation States | |---------|---|--------|------------------| | Cu | 29 | [Ar] 3d104s13d^{10} 4s^1 | +1, +2 (variable) | | Ti | 22 | [Ar] 3d24s23d^2 4s^2 | +2, +3, +4 (variable) | | Sc | 21 | [Ar] 3d14s23d^1 4s^2 | +3 only | | V | 23 | [Ar] 3d34s23d^3 4s^2 | +2, +3, +4, +5 (variable) |

Sc loses all 3 electrons to achieve the stable [Ar][\text{Ar}] configuration. It cannot show any other positive oxidation state — hence no variable oxidation states.

Answer: Option (3) — Sc

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