Chapter 13
Ch. 13 | Practical Organic Chemistry
What is Sublimation? Most substances follow a predictable path when heated: solid → liquid → gas.
Your journey through this chapter
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Sublimation
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Crystallisation
Using hot and cold solubility to pull pure crystals out of an impure mixture
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Distillation
Separating liquids by harnessing the difference in their boiling points
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Fractional Distillation
What to do when two liquids refuse to boil at very different temperatures
1 sim1 check - 5
Special Distillation Techniques
When the compound would decompose before it boils — or is stuck in water
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Differential Extraction
Pulling a compound out of water and into an organic solvent using solubility differences
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Chromatography
How a single technique can separate, identify, and purify compounds — all at once
1 sim1 check - 8
Qualitative Analysis of Organic Compounds
How chemists detect which elements are hiding inside an unknown organic compound
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Estimation of Carbon and Hydrogen
Burning a compound completely and weighing the products to find the % of C and H
1 example1 check - 10
Estimation of Nitrogen
Two methods — Dumas and Kjeldahl — each used in different situations
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Estimation of Halogens and Sulphur
The Carius method — heating with fuming nitric acid in a sealed tube
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Estimation of Phosphorus and Oxygen
Completing the picture — the last two elements, and how oxygen is usually found by subtraction
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